Let’s just agree to disagree on the “do girls approach guys” conversation since this thread is about PS ZP.
Going back to your planned stack for day game I think daredevil and primal seduction would work perfectly. I can’t speak for daredevil ZP but PS definitely gave me an urge to socialize more alongside a strong sexually charged state of being so I can only imagine that combining it with a sub that specifically addresses being active socially should bring tremendous results.
In my opinion that combo would lead to the user becoming very sexually forward, nonchalant and yet leading interactions forward towards their desired outcome.